LAUSR

Photonic crystals (PCs) are an important subset of photonic materials with specific optical properties, which can be utilized for structural color printing, anti-counterfeiting technologies, chemical sensors and so on. However, the fabrication of scalable, high-quality and uniform photonic crystal films at room temperature still remains a big challenge. Herein, a fast, energy efficient and scalable process is reported for the first time. A high-quality polymeric photonic crystal film can be fabricated from the uniform core/shell particle slurry within several seconds by a calendering process. The obtained crystalline structure can be rapidly captured by photo-curing, and the resultant PC films show extremely strong iridescent tunable structural colors. Because the as-designed PC film matrix is sensitive to solutions with different solubility parameters, a prototype demo sensor is firstly set up for quick detection of the composition of the alcohol/H2O mixture as a model of white spirits, which has the feature of reversible and linear quantitative sensing performance. In addition, the as-prepared PC film is further developed as an inexpensive test strip showing quick detection of ethanol/octane mixtures (possessing different solubility parameters) as a model of ethanol gasoline. This facile, scalable and energy efficient fabrication procedure is exceedingly promising for high-throughput production, showing great potential for industrialization of PC sensors and detectors. The combination of uniform particles and a dispersion medium can be potentially designed for different stimuli responsive systems, which is beneficial for applications ranging from sensing, anti-counterfeiting, to some special optical devices.