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Enhanced reduction of polymerization-induced shrinkage stress via combination of radical ring opening and addition fragmentation chain transfer

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The combination of vinylcyclopropanes with an ester-activated vinyl sulfonate ester in a light-induced radical polymerization shows high reactivity accompanied by a significant increase in conversion and it leads to an… Click to show full abstract

The combination of vinylcyclopropanes with an ester-activated vinyl sulfonate ester in a light-induced radical polymerization shows high reactivity accompanied by a significant increase in conversion and it leads to an enhanced reduction of polymerization-induced shrinkage stress.

Keywords: reduction polymerization; induced shrinkage; polymerization induced; polymerization; shrinkage stress; enhanced reduction

Journal Title: Polymer Chemistry
Year Published: 2019

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