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Two novel tetrahedral manganese(II) complexes, (N-methylpiperidinium)MnCl4 (1) and (N-methylpyrrolidinium)MnCl4 (2), with clearly distinct fluorescence characteristics were synthesized through organic cation modulation. Compound 1 exhibits prominent green luminescence with a high… Click to show full abstract
Two novel tetrahedral manganese(II) complexes, (N-methylpiperidinium)MnCl4 (1) and (N-methylpyrrolidinium)MnCl4 (2), with clearly distinct fluorescence characteristics were synthesized through organic cation modulation. Compound 1 exhibits prominent green luminescence with a high quantum yield of 79.37% and 2 emits unusual red emission at 611 nm.
Keywords:
unusual photoluminescence;
high quantum;
yield unusual;
quantum yield;
tetrahedral manganese
Journal Title: Inorganic chemistry frontiers
Year Published: 2018
Link to full text (if available)
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Journal Title: Inorganic chemistry frontiers
Year Published: 2018
Link to full text (if available)
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recommendations!