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A silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols including cyclopropanols, cyclobutanols, cyclopentanols, cyclohexanols and cycloheptanols was described. A variety of common functional groups such as fluoride, chloride, bromide, iodide, trifluoromethyl, cyano and… Click to show full abstract
A silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols including cyclopropanols, cyclobutanols, cyclopentanols, cyclohexanols and cycloheptanols was described. A variety of common functional groups such as fluoride, chloride, bromide, iodide, trifluoromethyl, cyano and ester groups were compatible.
Keywords:
silver catalyzed;
difluoromethylthiolation trifluoromethylthiolation;
ring opening;
trifluoromethylthiolation cycloalkanols;
catalyzed ring;
opening difluoromethylthiolation
Journal Title: Organic chemistry frontiers
Year Published: 2018
Link to full text (if available)
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Journal Title: Organic chemistry frontiers
Year Published: 2018
Link to full text (if available)
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recommendations!