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Photoredox-catalyzed cascade annulation of methyl(2-(phenylethynyl)phenyl)sulfanes and methyl(2-(phenylethynyl)phenyl)selanes with sulfonyl chlorides: synthesis of benzothiophenes and benzoselenophenes

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A photoredox-catalyzed cascade annulation of methyl(2-(phenylethynyl)phenyl)sulfanes and methyl(2-(phenylethynyl)phenyl)selanes with sulfonyl chlorides was developed. A variety of benzothiophenes and benzoselenophenes were obtained in moderate to good yields at ambient temperature. Click to show full abstract

A photoredox-catalyzed cascade annulation of methyl(2-(phenylethynyl)phenyl)sulfanes and methyl(2-(phenylethynyl)phenyl)selanes with sulfonyl chlorides was developed. A variety of benzothiophenes and benzoselenophenes were obtained in moderate to good yields at ambient temperature.

Keywords: methyl phenylethynyl; catalyzed cascade; phenylethynyl phenyl; cascade annulation; photoredox catalyzed

Journal Title: Organic chemistry frontiers
Year Published: 2018

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