Photo by benceboros from unsplash
A novel strategy for the dearomatization of naphthols using in situ generated oxy-allyl cations is reported. Both α- and β-naphthols can work well in this process. Using this catalyst-free methodology,… Click to show full abstract
A novel strategy for the dearomatization of naphthols using in situ generated oxy-allyl cations is reported. Both α- and β-naphthols can work well in this process. Using this catalyst-free methodology, various structurally diverse α-quaternary center-containing 2-(2-oxocycloalkyl)cycloalkyl diketones can be efficiently accessed in good to excellent yields under mild conditions.
Keywords:
dearomatization naphthols;
naphthols using;
allyl cations;
oxy allyl;
center containing;
quaternary center
Journal Title: Organic chemistry frontiers
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Organic chemistry frontiers
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!