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A straight-forward and atom-economical Cu(II)/PBQ-catalyzed oxidative phosphonation of 3,4-dihydro-1,4-benzoxazin-2-ones has been developed through an OEO involving oxidative Pudovik reaction. The experiments are performed under mild reaction conditions to construct new… Click to show full abstract
A straight-forward and atom-economical Cu(II)/PBQ-catalyzed oxidative phosphonation of 3,4-dihydro-1,4-benzoxazin-2-ones has been developed through an OEO involving oxidative Pudovik reaction. The experiments are performed under mild reaction conditions to construct new Csp3–P bonds and provide a new opportunity to obtain potentially bioactive α-aminophosphonates with a novel structure.
Keywords:
benzoxazin ones;
oxidative phosphonation;
dihydro benzoxazin;
phosphonation dihydro;
catalyzed oxidative
Journal Title: Organic chemistry frontiers
Year Published: 2018
Link to full text (if available)
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Journal Title: Organic chemistry frontiers
Year Published: 2018
Link to full text (if available)
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recommendations!