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A new method for α-specific glucosylation and its application to the one-pot synthesis of a branched α-glucan

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We have developed a new and highly efficient α-specific glucosylation method based on the synergistic α-directing effects of a TolSCl/AgOTf promoter system and the steric β-shielding or the remote participation… Click to show full abstract

We have developed a new and highly efficient α-specific glucosylation method based on the synergistic α-directing effects of a TolSCl/AgOTf promoter system and the steric β-shielding or the remote participation of protecting groups at the donor 6-O-position.

Keywords: new method; method specific; glucosylation; glucosylation application; specific glucosylation

Journal Title: Organic Chemistry Frontiers
Year Published: 2019

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