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Ir-Catalyzed ring-opening of oxa(aza)benzonorbornadienes with water or alcohols

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A highly efficient Ir-catalyzed ring-opening reaction of oxa(aza)benzonorbornadienes with water was firstly developed, which afforded a mild access to substituted dihydronaphthalene products with excellent yields (up to 99%) within 30… Click to show full abstract

A highly efficient Ir-catalyzed ring-opening reaction of oxa(aza)benzonorbornadienes with water was firstly developed, which afforded a mild access to substituted dihydronaphthalene products with excellent yields (up to 99%) within 30 min.

Keywords: aza benzonorbornadienes; benzonorbornadienes water; catalyzed ring; oxa aza; ring opening

Journal Title: Organic Chemistry Frontiers
Year Published: 2019

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