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Weak magnetic field enhances the activation of peroxymonosulfate by ZnO@Fe3O4

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The effect of weak magnetic field (WMF) on Acid Orange 7 (AO7) removal by ZnO@Fe3O4/peroxymonosulphate (PMS) was investigated. The results showed that the AO7 sequestration rate enhanced progressively to 0.14183… Click to show full abstract

The effect of weak magnetic field (WMF) on Acid Orange 7 (AO7) removal by ZnO@Fe3O4/peroxymonosulphate (PMS) was investigated. The results showed that the AO7 sequestration rate enhanced progressively to 0.14183 min−1 in the presence of WMF, approximately 3 times the 0.04966 min−1 in the absence of WMF. SO4˙−/SO5˙− and O2˙− radicals were generated from the decomposition of PMS catalyzed by ZnO@Fe3O4 causing the degradation of AO7. In addition, a weak magnetic field promoted the production of O2˙− radicals and transition of Fe3+ to Fe2+. Radical-pair theory was used in this study to describe the role of WMF and a possible reaction mechanism was derived. Based on that, the influence of magnetic field flux intensity, pH and the reusability of ZnO@Fe3O4 were investigated in this paper.

Keywords: weak magnetic; magnetic field; zno fe3o4

Journal Title: RSC Advances
Year Published: 2018

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