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Solvent-free hydrogenation of cyclohexene over Rh-TUD-1 at ambient conditions

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Rhodium nanoparticles (≈3–5 nm) were incorporated into the 3D mesoporous TUD-1 material by using sol–gel technique. The prepared catalyst shows high activity in the liquid phase conversion of cyclohexene to… Click to show full abstract

Rhodium nanoparticles (≈3–5 nm) were incorporated into the 3D mesoporous TUD-1 material by using sol–gel technique. The prepared catalyst shows high activity in the liquid phase conversion of cyclohexene to cyclohexane at room temperature (298 K), 1 atm H2 pressure, and under solvent-free conditions. Rhodium nanoparticles exhibited high stability, reusability and negligible leaching.

Keywords: tud ambient; cyclohexene tud; cyclohexene; hydrogenation cyclohexene; solvent free; free hydrogenation

Journal Title: RSC Advances
Year Published: 2018

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