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A radical relay strategy for mono- and di-halogenation (iodination, bromination, and chlorination) of sp3 C–H bonds has been developed. This first example of double, geminal C–H functionalization is enabled via… Click to show full abstract
A radical relay strategy for mono- and di-halogenation (iodination, bromination, and chlorination) of sp3 C–H bonds has been developed. This first example of double, geminal C–H functionalization is enabled via iterative, hydrogen atom transfer (HAT) by in situ generated imidate radicals.
Keywords:
atom transfer;
hydrogen atom;
via iterative;
iterative hydrogen;
esi;
halogenation
Journal Title: Chemical Science
Year Published: 2018
Link to full text (if available)
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Journal Title: Chemical Science
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!