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An enantioselective carbonyl-ene reaction of 1,1-disubstituted olefins with ethyl glyoxylate was accomplished using an F10BINOL-derived chiral phosphoric acid of which the perfluoro-binaphthyl skeleton is beneficial not only for adopting high… Click to show full abstract
An enantioselective carbonyl-ene reaction of 1,1-disubstituted olefins with ethyl glyoxylate was accomplished using an F10BINOL-derived chiral phosphoric acid of which the perfluoro-binaphthyl skeleton is beneficial not only for adopting high catalytic activity but also for creating an effective chiral environment.
Keywords:
carbonyl ene;
f10binol derived;
derived chiral;
chiral phosphoric;
enantioselective carbonyl;
ene reaction
Journal Title: Chemical Science
Year Published: 2019
Link to full text (if available)
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Journal Title: Chemical Science
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!