"Enantioselective synthesis of gem-disubstituted N-Boc diazaheterocycles via decarboxylative asymmetric allylic alkylation† †Electronic supplementary information (ESI) available: Experimental procedures, 1H NMR, 13C NMR, and IR spectra. See DOI: 10.1039/c8sc03967d"

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Enantioselective synthesis of gem-disubstituted N-Boc diazaheterocycles via decarboxylative asymmetric allylic alkylation† †Electronic supplementary information (ESI) available: Experimental procedures, 1H NMR, 13C NMR, and IR spectra. See DOI: 10.1039/c8sc03967d

An enantioselective synthesis of diverse N4-Boc-protected α,α-disubstituted piperazin-2-ones and tetrahydropyrimidin-2-ones using the palladiumcatalyzed decarboxylative allylic alkylation reaction has been achieved. Click to show full abstract

Keywords: gem disubstituted; synthesis gem; allylic alkylation; enantioselective synthesis

Journal Title: Chemical Science
Year Published: 2019

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