"Ni-catalyzed migratory fluoro-alkenylation of unactivated alkyl bromides with gem-difluoroalkenes† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc04162h"

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Ni-catalyzed migratory fluoro-alkenylation of unactivated alkyl bromides with gem-difluoroalkenes† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc04162h

A migratory fluoro-alkenylation of unactivated alkyl bromides is reported; the reaction is enabled by fluorine effects and involves an alkyl nickel chain-walking mechanism. Click to show full abstract

A migratory fluoro-alkenylation of unactivated alkyl bromides is reported; the reaction is enabled by fluorine effects and involves an alkyl nickel chain-walking mechanism.

Keywords: unactivated alkyl; alkenylation unactivated; alkyl bromides; fluoro alkenylation; migratory fluoro

Journal Title: Chemical Science
Year Published: 2019

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