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Metal-free visible light photoredox enables generation of carbyne equivalents via phosphonium ylide C–H activation† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc04195d

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Phosphonium ylides have shown their synthetic usefulness in important carbon–carbon bond formation processes. Our new strategy employs phosphonium ylides as novel carbyne equivalents and features a new approach for constructing… Click to show full abstract

Phosphonium ylides have shown their synthetic usefulness in important carbon–carbon bond formation processes. Our new strategy employs phosphonium ylides as novel carbyne equivalents and features a new approach for constructing carbon–carbon bonds from alkenes.

Keywords: carbon; phosphonium; free visible; carbyne equivalents; metal free

Journal Title: Chemical Science
Year Published: 2019

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