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Non-stabilized diazoalkane synthesis via the oxidation of free hydrazones by iodosylbenzene and application in in situ MIRC cyclopropanation† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc05558k

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Highly reactive non-stabilized diazo compounds are generated from free hydrazones using iodosylbenzene. In situ MIRC cyclopropanations were performed on a wide array of substrates. Click to show full abstract

Highly reactive non-stabilized diazo compounds are generated from free hydrazones using iodosylbenzene. In situ MIRC cyclopropanations were performed on a wide array of substrates.

Keywords: non stabilized; situ mirc; diazoalkane synthesis; stabilized diazoalkane; free hydrazones

Journal Title: Chemical Science
Year Published: 2019

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