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Deep blue thermally activated delayed fluorescent emitters using CN-modified indolocarbazole as an acceptor and carbazole-derived donors

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Deep blue thermally activated delayed fluorescent (TADF) emitters having carbazole derivatives as donors and CN-modified indolocarbazole as an acceptor were developed. Indolocarbazole moiety modified by CN was an acceptor of… Click to show full abstract

Deep blue thermally activated delayed fluorescent (TADF) emitters having carbazole derivatives as donors and CN-modified indolocarbazole as an acceptor were developed. Indolocarbazole moiety modified by CN was an acceptor of all the carbazole-based TADF emitters, and carbazole and t-butylcarbazole were donors combined with the CN-modified indolocarbazole. The carbazole-based TADF emitters showed a narrow emission spectrum with a less than 60 nm full width at half maximum, deep blue emission color with a y color coordinate below 0.13, and a high external quantum efficiency of 16.0%.

Keywords: deep blue; carbazole; modified indolocarbazole; blue thermally; acceptor

Journal Title: Journal of Materials Chemistry C
Year Published: 2018

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