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Gold(ii) species catalyse the cyclisation of N(2-propyn-1-yl)benzamide to 2-phenyl-5-vinylidene-2-oxazoline without halide abstraction while the saturated gold(i) complex is inactive. Redox-switching between gold(ii) and gold(i) turns catalytic turnover on and off. Click to show full abstract
Gold(ii) species catalyse the cyclisation of N(2-propyn-1-yl)benzamide to 2-phenyl-5-vinylidene-2-oxazoline without halide abstraction while the saturated gold(i) complex is inactive. Redox-switching between gold(ii) and gold(i) turns catalytic turnover on and off.
Keywords:
switchable gold;
gold redox;
redox switchable;
gold catalysis;
redox;
gold
Journal Title: Chemical communications
Year Published: 2019
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!