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DNP NMR spectroscopy reveals new structures, residues and interactions in wild spider silks.

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DNP solid state NMR spectroscopy allows non-targeted analysis of wild spider silk in unprecedented detail at natural abundance, revealing hitherto unreported features across several species. A >50-fold signal enhancement for… Click to show full abstract

DNP solid state NMR spectroscopy allows non-targeted analysis of wild spider silk in unprecedented detail at natural abundance, revealing hitherto unreported features across several species. A >50-fold signal enhancement for each silk, enables the detection of novel H-bonding networks and arginine conformations, and the post-translational modified amino acid, hydroxyproline.

Keywords: nmr spectroscopy; wild spider; spectroscopy; dnp nmr; spectroscopy reveals

Journal Title: Chemical communications
Year Published: 2019

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