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MOF-templated self-polymerization of p-phenylenediamine to a polymer with a hollow box-assembled spherical structure.

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This paper presents the first transformation of MOFs to polymers without any additives by using a one-step MOF-templated self-polymerization approach. We investigate the conversion process and demonstrate that the MOF-templated… Click to show full abstract

This paper presents the first transformation of MOFs to polymers without any additives by using a one-step MOF-templated self-polymerization approach. We investigate the conversion process and demonstrate that the MOF-templated self-polymerization is a new and effective approach for the in situ conversion of organic ligands to polymers and even carbon nanomaterials with maintained MOF configurations.

Keywords: polymerization phenylenediamine; phenylenediamine polymer; templated self; self polymerization; mof templated

Journal Title: Chemical communications
Year Published: 2019

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