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Herein, we, for the first time, report a high spin Co-Fe Prussian blue analogue (Co-Fe PBA) as a highly efficient Fenton-like catalyst for sulfate radical (SO4˙-) production. Our experiments and… Click to show full abstract
Herein, we, for the first time, report a high spin Co-Fe Prussian blue analogue (Co-Fe PBA) as a highly efficient Fenton-like catalyst for sulfate radical (SO4˙-) production. Our experiments and density functional theory (DFT) calculations show that the largely elongated SO4-OH bond length, strengthened adsorption and facilitated electron transfer for peroxymonosulfate (PMS) activation catalyzed by high-spin (HS) CoII are the main factors contributing to its excellent activity.
Keywords:
high spin;
fenton like;
prussian blue;
spin;
efficient fenton;
blue analogue
Journal Title: Chemical communications
Year Published: 2019
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!