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From a volatile molecular precursor to twin-free single crystals of bismuth.

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A highly volatile molecular precursor, dibismuth(ii) (tetra)trifluoroacetate, was successfully utilized for the gas phase growth of twin-free single crystals of bismuth. This allowed high-quality single-crystal X-ray diffraction data to be… Click to show full abstract

A highly volatile molecular precursor, dibismuth(ii) (tetra)trifluoroacetate, was successfully utilized for the gas phase growth of twin-free single crystals of bismuth. This allowed high-quality single-crystal X-ray diffraction data to be collected, providing accurate structural parameters for elemental bismuth under ambient conditions.

Keywords: volatile molecular; molecular precursor; free single; single crystals; crystals bismuth; twin free

Journal Title: Chemical communications
Year Published: 2019

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