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Probing the guest-binding preference of three structurally similar and conformationally adaptive macrocycles.

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A hybrid macrocycle was synthesized by combining the repeat units in oxatub[4]arene and zorb[4]arene, and its recognition behavior and conformational analysis were studied. Three structurally similar and conformationally adaptive macrocycles… Click to show full abstract

A hybrid macrocycle was synthesized by combining the repeat units in oxatub[4]arene and zorb[4]arene, and its recognition behavior and conformational analysis were studied. Three structurally similar and conformationally adaptive macrocycles show different guest-binding selectivities and preferences even in a complex mixture containing three macrocycles and three guests.

Keywords: conformationally adaptive; similar conformationally; guest binding; structurally similar; three structurally; adaptive macrocycles

Journal Title: Chemical communications
Year Published: 2019

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