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Reported herein is a cascade Lewis acid-promoted intramolecular Friedel-Crafts-type imidoylation and Rh(iii)-catalyzed C-H activation/annulation of benzimidoyl chlorides and alkynes, providing a general and concise one-pot approach to 7H-dibenzo[de,h]quinoline analogues. This… Click to show full abstract
Reported herein is a cascade Lewis acid-promoted intramolecular Friedel-Crafts-type imidoylation and Rh(iii)-catalyzed C-H activation/annulation of benzimidoyl chlorides and alkynes, providing a general and concise one-pot approach to 7H-dibenzo[de,h]quinoline analogues. This divergent approach is based on a convergent retrosynthetic disconnection strategy.
Keywords:
annulation benzimidoyl;
dibenzo quinoline;
chlorides alkynes;
activation annulation;
one pot;
benzimidoyl chlorides
Journal Title: Chemical communications
Year Published: 2019
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!