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Converting Mn/Al layered double hydroxide anion exchangers into cation exchangers by topotactic reactions using alkali metal sulfate solutions.

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Layered double hydroxides (LDHs), traditional anion exchangers, can be converted into cation exchangers by topotactic reactions using aqueous solutions of alkali metal sulfates. LDHs with the composition [Mn2Al(OH)6](An-)1/n·yH2O (An- =… Click to show full abstract

Layered double hydroxides (LDHs), traditional anion exchangers, can be converted into cation exchangers by topotactic reactions using aqueous solutions of alkali metal sulfates. LDHs with the composition [Mn2Al(OH)6](An-)1/n·yH2O (An- = Cl- or NO3-, CO32-) were reacted with aqueous solutions of Na2SO4. The anion carbonate could only be partially replaced by sulfate.

Keywords: anion; layered double; exchangers topotactic; topotactic reactions; cation exchangers; anion exchangers

Journal Title: Chemical communications
Year Published: 2019

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