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PINO/NHPI-mediated selective oxidation of cycloalkenes to cycloalkenones via a photo-electrochemical method.

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The selective photo-electrochemical oxidation of cyclohexene to 2-cyclohexene-1-one was successfully performed with excellent Faraday efficiency (>99%) via indirect oxidation with a PINO/NHPI mediator and O2 on a BiVO4/WO3 photoanode under… Click to show full abstract

The selective photo-electrochemical oxidation of cyclohexene to 2-cyclohexene-1-one was successfully performed with excellent Faraday efficiency (>99%) via indirect oxidation with a PINO/NHPI mediator and O2 on a BiVO4/WO3 photoanode under low applied bias.

Keywords: oxidation; photo electrochemical; mediated selective; nhpi mediated; pino nhpi

Journal Title: Chemical communications
Year Published: 2019

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