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A heavy metal-free CuInS2 quantum dot sensitized NiO photocathode with a Re molecular catalyst for photoelectrochemical CO2 reduction.

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Heavy metal-free CuInS2 quantum dots (QDs) were employed as a photosensitizer on a NiO photocathode to drive an immobilized molecular Re catalyst for photoelectrochemical CO2 reduction for the first time.… Click to show full abstract

Heavy metal-free CuInS2 quantum dots (QDs) were employed as a photosensitizer on a NiO photocathode to drive an immobilized molecular Re catalyst for photoelectrochemical CO2 reduction for the first time. A photocurrent of 25 μA cm-2 at -0.87 V vs. NHE was obtained, providing a faradaic efficiency of 32% for CO production.

Keywords: cuins2 quantum; molecular catalyst; free cuins2; heavy metal; metal free; nio photocathode

Journal Title: Chemical communications
Year Published: 2019

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