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The 3.5 nm-sized polyanion [H4TeIV48WVI78O372]80-, exhibiting an exceptionally high Te : W ratio, expands the structural role of TeIV ions from classical heterogroups within polyoxotungstate subunits to addenda ions. Investigations on the… Click to show full abstract
The 3.5 nm-sized polyanion [H4TeIV48WVI78O372]80-, exhibiting an exceptionally high Te : W ratio, expands the structural role of TeIV ions from classical heterogroups within polyoxotungstate subunits to addenda ions. Investigations on the self-assembly conditions, proceeding in a simple one-pot reaction, point to the pH as one critical factor for circumventing this limitation.
Keywords:
blurring line;
giant polyoxotungstotellurite;
line addenda;
heteroatoms giant;
addenda heteroatoms
Journal Title: Chemical communications
Year Published: 2019
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Journal Title: Chemical communications
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!