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Anion and pH dependent molecular motion by a halogen bonding [2]rotaxane.

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A bistable [2]rotaxane containing a halogen bonding benzimidazole-iodotriazole station directly conjugated to a naphthalimide station axle component is demonstrated to undergo macrocycle shuttling translocation only upon both protonation and chloride… Click to show full abstract

A bistable [2]rotaxane containing a halogen bonding benzimidazole-iodotriazole station directly conjugated to a naphthalimide station axle component is demonstrated to undergo macrocycle shuttling translocation only upon both protonation and chloride anion recognition. A naked-eye detectable colour response results from the co-conformational change of the host structure.

Keywords: dependent molecular; anion dependent; rotaxane; halogen bonding

Journal Title: Chemical communications
Year Published: 2019

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