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The selective synthesis of the zinc-acetato-phosphinidene cluster [Zn6(μ3-PSiMe3)4(OAc)4(NC5H5)5] 1 is presented. The cluster serves as a stable, single-source precursor to yield soluble zinc phosphide nanoparticles via P-Si bond activation and… Click to show full abstract
The selective synthesis of the zinc-acetato-phosphinidene cluster [Zn6(μ3-PSiMe3)4(OAc)4(NC5H5)5] 1 is presented. The cluster serves as a stable, single-source precursor to yield soluble zinc phosphide nanoparticles via P-Si bond activation and AcOSiMe3 elimination when heated in oleylamine or other donor solvents.
Keywords:
single source;
zinc;
zinc acetato;
source precursor;
synthesis
Journal Title: Chemical communications
Year Published: 2019
Link to full text (if available)
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Journal Title: Chemical communications
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!