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Photo-induced electron transfer in a metal-organic framework: a new approach towards a highly sensitive luminescent probe for Fe3.

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A Co-based mixed-ligand metal-organic framework (MOF), ZJU-109, is reported by utilizing 6-(4-pyridyl)-terephthalic acid (H2pta) and 4,4'-bis(imidazolyl)biphenyl (4,4'-bimbp) as double linkers. By tuning the d-PET process between ligands 4,4'-bimbp and H2pta,… Click to show full abstract

A Co-based mixed-ligand metal-organic framework (MOF), ZJU-109, is reported by utilizing 6-(4-pyridyl)-terephthalic acid (H2pta) and 4,4'-bis(imidazolyl)biphenyl (4,4'-bimbp) as double linkers. By tuning the d-PET process between ligands 4,4'-bimbp and H2pta, a fluorescent turn-on sensor for Fe3+ with a detection limit as low as 0.053 μM has been demonstrated.

Keywords: photo induced; induced electron; metal organic; organic framework

Journal Title: Chemical communications
Year Published: 2019

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