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DABCO-mediated [3+3] cycloaddition of azomethine imines with in situ generated nitrile oxides from hydroximoyl chlorides.

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A novel cross 1,3-dipolar cycloaddition between azomethine imines with in situ generated nitrile oxides has been developed. This is the first example of employing a reaction partner containing two heteroatoms… Click to show full abstract

A novel cross 1,3-dipolar cycloaddition between azomethine imines with in situ generated nitrile oxides has been developed. This is the first example of employing a reaction partner containing two heteroatoms in the [3+3] cycloaddition involving azomethine imines. This strategy not only provides structurally diverse N,O-heterocycles but also greatly enriches the chemistry of azomethine imines and nitrile oxides.

Keywords: nitrile oxides; azomethine imines; cycloaddition azomethine; imines situ

Journal Title: Chemical communications
Year Published: 2019

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