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Small triiminopyrrolic molecular cage with high affinity and selectivity for fluoride.

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A small molecular cage (4) with high affinity and complete selectivity for fluoride to the limit of detection over other competing small anions was synthesized. Cage 4 was also found… Click to show full abstract

A small molecular cage (4) with high affinity and complete selectivity for fluoride to the limit of detection over other competing small anions was synthesized. Cage 4 was also found to retain the encapsulated fluoride anion within its cavity even after one or two pyrrolic NH protons were subject to deprotonation.

Keywords: high affinity; molecular cage; cage high; cage; selectivity fluoride

Journal Title: Chemical communications
Year Published: 2019

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