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Secondary phosphine oxides stabilized Au/Pd nanoalloys: metal components-controlled regioselective hydrogenation toward phosphinyl (Z)-[3]dendralenes.

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A series of gold/palladium nanoalloys stabilized by secondary phosphine oxides have been prepared for the first time. The nanocatalysts exhibit excellent regio- and chemo-selectivity in the hydrogenation of conjugated enynes,… Click to show full abstract

A series of gold/palladium nanoalloys stabilized by secondary phosphine oxides have been prepared for the first time. The nanocatalysts exhibit excellent regio- and chemo-selectivity in the hydrogenation of conjugated enynes, providing a mild and highly efficient way to access phosphinyl (Z) and (Z,Z)-[3]dendralenes.

Keywords: oxides stabilized; hydrogenation; phosphinyl dendralenes; secondary phosphine; phosphine oxides

Journal Title: Chemical communications
Year Published: 2019

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