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Revisiting the water sorption isotherm of MOF using electrical measurements.

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Water adsorption/desorption isotherms of Cr-soc-MOF-1 were monitored electrically, with the translation of proton conductivity measurements to physisorption isotherms in terms of S-shape and hysteresis features revealed by volumetry. Molecular modelling… Click to show full abstract

Water adsorption/desorption isotherms of Cr-soc-MOF-1 were monitored electrically, with the translation of proton conductivity measurements to physisorption isotherms in terms of S-shape and hysteresis features revealed by volumetry. Molecular modelling further established the relationship between the evolutive water-hydrogen bonded network and the "electrical" isotherm for this water-mediated proton conducting MOF.

Keywords: revisiting water; water; isotherm mof; sorption isotherm; water sorption; isotherm

Journal Title: Chemical communications
Year Published: 2019

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