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There is nothing wrong with being soft: using sulfur ligands to increase axiality in a Dy(iii) single-ion magnet.

A new air-stable sulfur-ligated Dy(iii) single-ion magnet has been successfully isolated with Ueff = 638 K and hysteresis loops open up to 7 K. In silico studies show that the… Click to show full abstract

A new air-stable sulfur-ligated Dy(iii) single-ion magnet has been successfully isolated with Ueff = 638 K and hysteresis loops open up to 7 K. In silico studies show that the S co-ligands significantly boost the axiality and that Te- and Se-donors have the potential to further enhance the magnetic properties.

Keywords: axiality; iii single; single ion; ion magnet

Journal Title: Chemical communications
Year Published: 2020

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