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Engineering Frenkel defects of anti-perovskite solid-state electrolytes and their applications in all-solid-state lithium-ion batteries.

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Fluorinated lithium-rich anti-perovskite (F-LiRAP) is proposed to enhance lithium ion conductivity by creating Frenkel defects that facilitate the formation of lithium-rich and lithium-vacancy couples. We successfully demonstrate an all-solid-state cell… Click to show full abstract

Fluorinated lithium-rich anti-perovskite (F-LiRAP) is proposed to enhance lithium ion conductivity by creating Frenkel defects that facilitate the formation of lithium-rich and lithium-vacancy couples. We successfully demonstrate an all-solid-state cell configuration based on F-LiRAP, precluding the employment of polymer or liquid additives.

Keywords: solid state; lithium; anti perovskite; frenkel defects; lithium ion

Journal Title: Chemical communications
Year Published: 2020

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