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Tracing and elucidating visible-light mediated oxidation and C-H functionalization of amines using mass spectrometry.

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The co-existing mechanism of visible light mediated direct oxidation and C-H functionalization of amines was investigated by capturing all the intermediates using online mass spectrometry. The two-step dehydrogenation of amine… Click to show full abstract

The co-existing mechanism of visible light mediated direct oxidation and C-H functionalization of amines was investigated by capturing all the intermediates using online mass spectrometry. The two-step dehydrogenation of amine involving a proton coupled electron transfer (PCET) process was revealed for the first time.

Keywords: mass spectrometry; light mediated; visible light; functionalization amines; oxidation functionalization

Journal Title: Chemical communications
Year Published: 2020

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