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Optimizing the surface state of cobalt-iron bimetallic phosphide via regulating phosphorus vacancies.

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Herein, we successfully regulated phosphorus vacancies in Co0.68Fe0.32P through Ar-plasma treatment. The Ar-plasma treated Co0.68Fe0.32P exhibits a delicate surface state where the surface Co and Fe ions show an unusual… Click to show full abstract

Herein, we successfully regulated phosphorus vacancies in Co0.68Fe0.32P through Ar-plasma treatment. The Ar-plasma treated Co0.68Fe0.32P exhibits a delicate surface state where the surface Co and Fe ions show an unusual electron loss. The unique surface state enhances the oxygen evolving performance of the phosphide.

Keywords: phosphorus vacancies; surface; optimizing surface; surface state

Journal Title: Chemical communications
Year Published: 2020

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