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Chloranilate bridged dinuclear copper(ii) complexes: syn–anti geometry tuned by the steric factor and supramolecular interactions

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The anti-conformation of chloranilate bridged di-copper complexes of NNO donor Schiff-base ligands is more stable than the syn-conformation, but the latter is stabilised by CH⋯π and hydrogen bonding interactions between… Click to show full abstract

The anti-conformation of chloranilate bridged di-copper complexes of NNO donor Schiff-base ligands is more stable than the syn-conformation, but the latter is stabilised by CH⋯π and hydrogen bonding interactions between solvent of crystallisation and chloranilate moieties.

Keywords: copper complexes; geometry; dinuclear copper; chloranilate bridged; bridged dinuclear

Journal Title: CrystEngComm
Year Published: 2019

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