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We have demonstrated the design of a novel bifunctional catalyst that is based on an N-confused tetraphenylporphyrin (NCTPP) motif for the cycloaddition of an epoxide to carbon dioxide via cooperative… Click to show full abstract
We have demonstrated the design of a novel bifunctional catalyst that is based on an N-confused tetraphenylporphyrin (NCTPP) motif for the cycloaddition of an epoxide to carbon dioxide via cooperative activation of the epoxide through a Pd(ii) or Ni(ii) metal center and a peripheral benzoate moiety with percent conversions of up to 99% and TON = 7000.
Keywords:
complexes catalysts;
cyclic carbonates;
confused porphyrin;
synthesis cyclic;
porphyrin complexes;
catalysts synthesis
Journal Title: Dalton transactions
Year Published: 2019
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!