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Two dinuclear lanthanide complexes (Gd and Dy) were prepared and characterized by X-ray, magnetic and computational methods. The Dy analogue shows SMM behavior with an energy barrier of 98.4 K… Click to show full abstract
Two dinuclear lanthanide complexes (Gd and Dy) were prepared and characterized by X-ray, magnetic and computational methods. The Dy analogue shows SMM behavior with an energy barrier of 98.4 K in the absence of an applied dc field. Theoretical calculations were performed on model complexes which support the hypothesis that the energy barrier will increase if the soft-donor atoms S and Se are used in lieu of an O donor.
Keywords:
versus soft;
field;
soft zero;
hard versus;
zero field;
field dinuclear
Journal Title: Dalton transactions
Year Published: 2019
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!