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The hypersensitive 2F5/2 to 2F7/2 transition of Yb3+ can be used to monitor perturbations of the coordination sphere in ytterbium(iii) complexes. An envelope of Stark components gives rise to a… Click to show full abstract
The hypersensitive 2F5/2 to 2F7/2 transition of Yb3+ can be used to monitor perturbations of the coordination sphere in ytterbium(iii) complexes. An envelope of Stark components gives rise to a relatively broad and asymmetric emission band, whilst changes in their relative intensity and energy enable a ratiometric response. We report a new ytterbium complex with a sulphonamide arm that binds reversibly to Yb3+ as a function of pH, giving rise to significant pH dependent changes in the Yb emission spectrum.
Keywords:
ytterbium;
ytterbium probe;
luminescent ratiometric;
ratiometric ytterbium;
near luminescent
Journal Title: Dalton transactions
Year Published: 2019
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Journal Title: Dalton transactions
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!