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Synthesis, structure and magnetic properties of a series of Ln(iii) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization.

We report the investigation of synthesis, structure and magnetic properties of a series of homoleptic Ln(iii) complexes coordinated by radical-anionic iminopyridine ligands of general formula [Ln(IPy)3]·solv (IPy = iminopyridine; Ln… Click to show full abstract

We report the investigation of synthesis, structure and magnetic properties of a series of homoleptic Ln(iii) complexes coordinated by radical-anionic iminopyridine ligands of general formula [Ln(IPy)3]·solv (IPy = iminopyridine; Ln = Tb, Dy, Er, Y, Gd). The dysprosium analogue exhibits a zero-field Single-Molecule Magnet (SMM) behavior.

Keywords: magnetic properties; iii complexes; synthesis structure; structure magnetic; radical anionic; properties series

Journal Title: Dalton transactions
Year Published: 2019

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