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Rhenium tricarbonyl bipyridine complexes modified with pendant secondary and tertiary amines in the 6- and 6'-positions were synthesized and characterized. Electrocatalytic studies performed under CO2 with 2,2,2-trifluoroethanol display large current… Click to show full abstract
Rhenium tricarbonyl bipyridine complexes modified with pendant secondary and tertiary amines in the 6- and 6'-positions were synthesized and characterized. Electrocatalytic studies performed under CO2 with 2,2,2-trifluoroethanol display large current densities, corresponding to the reduction of CO2 to CO with moderate faradaic efficiencies (51-73%).
Keywords:
bonding pendant;
bipyridine catalysts;
rhenium bipyridine;
reduction;
catalysts hydrogen;
hydrogen bonding
Journal Title: Dalton transactions
Year Published: 2019
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!