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The first alkali-earth metal lead(ii) oxyhalide Ba8SrPb24O24Cl18 characterized by fascinating multimember-ring layers has been discovered. Theoretical and experimental investigations illustrate that Ba8SrPb24O24Cl18 exhibits a moderate band gap of 3.09 eV,… Click to show full abstract
The first alkali-earth metal lead(ii) oxyhalide Ba8SrPb24O24Cl18 characterized by fascinating multimember-ring layers has been discovered. Theoretical and experimental investigations illustrate that Ba8SrPb24O24Cl18 exhibits a moderate band gap of 3.09 eV, incongruent melting behavior and birefringence of 0.014@1064 nm. This discovery may offer new ideas for regulating the optical properties of oxyhalides and broadening their structural diversity.
Keywords:
lead oxyhalide;
metal lead;
earth metal;
multimember ring;
alkali earth;
first alkali
Journal Title: Dalton transactions
Year Published: 2019
Link to full text (if available)
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Journal Title: Dalton transactions
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!