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Reversible turn-on fluorescent Cu(ii) sensors: rather dream than reality?

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Reversible turn-on fluorescent sensors of Cu(ii) are of high interest for biological studies. We re-investigate a reported sensor, showing that turn-on occurs via irreversible Cu(ii)-induced sensor oxidation only in the… Click to show full abstract

Reversible turn-on fluorescent sensors of Cu(ii) are of high interest for biological studies. We re-investigate a reported sensor, showing that turn-on occurs via irreversible Cu(ii)-induced sensor oxidation only in the presence of acetonitrile. This prevents its application in biological studies and highlights the challenge of establishing a reversible Cu(ii) turn-on sensor.

Keywords: turn fluorescent; reversible turn; fluorescent sensors; sensors rather; rather dream; turn

Journal Title: Dalton transactions
Year Published: 2019

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