Photo by louishansel from unsplash
The mononuclear cyclic (alkyl)(amino)carbene (cAAC) supported titanium(iii) chloride complex [(cAAC)2TiCl3] has been synthesized by treatment of free cAAC with TiCl3(THF)3. Further reduction of (cAAC)2TiCl3 with potassium graphite (KC8) afforded the… Click to show full abstract
The mononuclear cyclic (alkyl)(amino)carbene (cAAC) supported titanium(iii) chloride complex [(cAAC)2TiCl3] has been synthesized by treatment of free cAAC with TiCl3(THF)3. Further reduction of (cAAC)2TiCl3 with potassium graphite (KC8) afforded the desired (cAAC)2TiCl2 complex, which features a small S-T energy gap. Both complexes were structurally characterized and represent the first cAAC supported Ti complexes.
Keywords:
amino carbene;
supported titanium;
mononuclear cyclic;
alkyl amino;
cyclic alkyl
Journal Title: Dalton transactions
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Dalton transactions
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!