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Metal β-diketonate complexes as highly efficient catalysts for chemical fixation of CO2 into cyclic carbonates under mild conditions.

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The potential of metal β-diketonate complexes for the catalysis of the chemical fixation of CO2 into cyclic carbonates at 1 atm CO2 and near room temperature was demonstrated. Their potential… Click to show full abstract

The potential of metal β-diketonate complexes for the catalysis of the chemical fixation of CO2 into cyclic carbonates at 1 atm CO2 and near room temperature was demonstrated. Their potential for the capture and simultaneous conversion of CO2 in a dilute CO2 stream was also determined. The catalysts were easily synthesized and commercially available. Therefore, this CO2 transformation was less energy- and material-consuming, which made this reaction closer to true "green" chemistry.

Keywords: fixation co2; co2 cyclic; diketonate complexes; chemical fixation; metal diketonate; cyclic carbonates

Journal Title: Dalton transactions
Year Published: 2019

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